By W.C.D. WHETHAM, M.A., F.R.S.
Trinity College, Cambridge.
The idea of evolution in the organic world, made intelligible by the work of Charles Darwin, has little in common with the recent conception of change in certain types of matter. The discovery that a process of disintegration may take place in some at least of the chemical atoms, previously believed to be indestructible and unalterable, has modified our view of the physical universe, even as Darwin's scheme of the mode of evolution changed the trend of thought concerning the organic world. Both conceptions have in common the idea of change throughout extended realms of space and time, and, therefore, it is perhaps not unfitting that some account of the most recent physical discoveries should be included in the present volume.
The earliest conception of the evolution of matter is found in the speculation of the Greeks. Leucippus and Democritus imagined unchanging eternal atoms, Heracleitus held that all things were in a continual state of flux--Panta rei.
But no one in the Ancient World--no one till quite modern times--could appreciate the strength of the position which the theory of the evolution of matter must carry before it wins the day. Vague speculation, even by the acute minds of philosophers, is of little use in physical science before experimental facts are available. The true problems at issue cannot even be formulated, much less solved, till the humble task of the observer and experimenter has given us a knowledge of the phenomena to be explained.
It was only through the atomic theory, at first apparently diametrically opposed to it, that the conception of evolution in the physical world was to gain an established place. For a century the atomic theory, when put into a modern form by Dalton, led farther and farther away from the idea of change in matter. The chemical elements seemed quite unalterable, and the atoms, of which each element in modern view is composed, bore to Clerk Maxwell, writing about 1870, "the stamp of manufactured articles" exactly similar in kind, unchanging, eternal.
Nevertheless throughout these years, on the whole so unfavourable to its existence, there persisted the idea of a common origin of the distinct kinds of matter known to chemists. Indeed, this idea of unity in substance in nature seems to accord with some innate desire or intimate structure of the human mind. As Mr Arthur Balfour well puts it, "There is no a priori reason that I know of for expecting that the material world should be a modification of a single medium, rather than a composite structure built out of sixty or seventy elementary substances, eternal and eternally different. Why then should we feel content with the first hypothesis and not with the second? Yet so it is. Men of science have always been restive under the multiplication of entities. They have eagerly watched for any sign that the different chemical elements own a common origin, and are all compounded out of some primordial substance. Nor, for my part, do I think that such instincts should be ignored...that they exist is certain;that they modify the indifferent impartiality of pure empiricism can hardly be denied." ("Report of the 74th Meeting of the British Association"(Presidential Address, Cambridge 1904), page 9, London, 1905.)When Dalton's atomic theory had been in existence some half century, it was noted that certain numerical relations held good between the atomic weights of elements chemically similar to one another. Thus the weight (88) of an atom of strontium compared with that of hydrogen as unity, is about the mean of those of calcium (40) and barium (137). Such relations, in this and other chemical groups, were illustrated by Beguyer de Chancourtois in 1862 by the construction of a spiral diagram in which the atomic weights are placed in order round a cylinder and elements chemically similar are found to fall on vertical lines.
Newlands seems to have been the first to see the significance of such a diagram. In his "law of octaves," formulated in 1864, he advanced the hypothesis that, if arranged in order of rising atomic weight, the elements fell into groups, so that each eighth element was chemically similar.
Stated thus, the law was too definite; no room was left for newly-discovered elements, and some dissimilar elements were perforce grouped together.
But in 1869 Mendeleeff developed Newland's hypothesis in a form that attracted at once general attention. Placing the elements in order of rising atomic weight, but leaving a gap where necessary to bring similar elements into vertical columns, he obtained a periodic table with natural vacancies to be filled as new elements were discovered, and with a certain amount of flexibility at the ends of the horizontal lines. From the position of the vacancies, the general chemical and physical properties of undiscovered elements could be predicted, and the success of such predictions gave a striking proof of the usefulness of Mendeleeff's generalisation.
When the chemical and physical properties of the elements were known to be periodic functions of their atomic weights, the idea of a common origin and common substance became much more credible. Differences in atomic weight and differences in properties alike might reasonably be explained by the differences in the amount of the primordial substance present in the various atoms; an atom of oxygen being supposed to be composed of sixteen times as much stuff as the atom of hydrogen, but to be made of the same ultimate material. Speculations about the mode of origin of the elements now began to appear, and put on a certain air of reality. Of these speculations perhaps the most detailed was that of Crookes, who imagined an initial chaos of a primordial medium he named protyle, and a process of periodic change in which the chemical elements successively were precipitated.
